Episode 1: The Honeymoon's Over.
Air Date: Oct 5, 2000
While Piper is on holiday with Leo in another plane, Prue and Phoebe must face a series of deamons known as Guardians, who protect mortal murderers in exchange for the souls of innocents. After saving Daryl from a Guardian, Prue and Phoebe must testify in court, where they stumble upon an evil conspiracy. Phoebe falls in love with the District Attorney - Cole Turner. Eventually, Piper returns from her holiday believing she has been gone for a day, when she has actually been missing for over a month. She later reveals that The Powers That Be delivered an ultimatum - either Piper and Leo end their relationship, or Leo is reassigned permanently, and the sisters get a new Whitelighter. To defy this order, Leo proposes to Piper in secret, since The Powers That Be cannot break a holy union between two people. Phoebe gains a new power - Levitation, and Piper gains the ability to selectively freeze people based on their morality.
Episode 2: Magic Hour
Air Date: Oct 12, 2000
The sisters must find a way to break a curse which turns a man into an Owl by day and his girlfriend into a Wolf by night. Meanwhile, Prue discovers a way to hold Piper and Leo's wedding without 'The Powers That Be' finding out.
Episode 6: Primrose Empath
Air Date: Nov 9, 2000
After casting a spell to save an empath from feeling the emotions of the entire city, the man she frees reveals himself to be an near-invincible warlock. Meanwhile, Phoebe's relationship with Cole becomes turbulent when Cole tells Phoebe he doesn't want to see her anymore. With Prue's empathic powers growing, she urges Phoebe to go after Cole and save their relationship. Within a few hours, Prue's spell backfires as the warlock intended, causing her and her powers to lose control.
Episode 9: Coyote Piper
Air Date: Jan 11, 2001
Piper is possessed by the spirit of an evil witch on the day of her High School reunion.
Episode 11: Blinded By The Whitelighter
Air Date: Jan 25, 2001
The sisters must stop a Warlock from executing his plan to steal specific powers from witches in his attempt to kill every White Lighter in the world.
Episode 12: Wrestling With Demons
Air Date: Feb 2, 2001
Prue's old boyfriend is going around killing specific people using his powers, however he was always mortal. Prue is destined to deliver him from the evil which has promised him his dreams.
Episode 15: Just Harried
Air Date: Feb 22, 2001
On the day of Piper's marriage to Leo, Prue's Astrally Projected-self adopts an uninhibited, wild personality that threatens to ruin the wedding and place Prue in jail for Murder.
Episode 16: Death Takes A Halliwell
Air Date: Mar 15, 2001
Prue must come to grips with the death of her mother when she is able to see the Angel of Death. Meanwhile demons called The Seekers are in town to look for info about Cole's whereabouts.
Episode 17: Pre-witched
Air Date: Mar 22, 2001
When a witch's familiar turns evil, the human product tries to get himself killed by the Halliwells nine times. Should he succeed, he will become a powerful and immortal warlock. Meanwhile, three and a half years in the past, before the sisters' powers were released, Grams, Prue and Piper must come to grips with the the departure of Phoebe to New York after her arrest for shoplifting, and the ill-health of Grams.
Episode 18: Sin Francisco
Air Date: Apr 19, 2001
A demon is making people become the embodiment of each of the deadly sins. Phoebe becomes the embodiment of Lust, Piper becomes the embodiment of gluttony, Prue becomes the embodiment of pride, and Leo becomes the embodiment of sloth.
Episode 19: The Demon Who Came In From The Cold
Air Date: Apr 26, 2001
Cole poses as Belthazar to infiltrate an internet organisation run by evil which plans on controlling the world's information flow on the internet. The sisters must vanquish the Warlock posing as the company's manager without exposing Cole's role in the situation.
Episode 20: Exit Strategy
Air Date: May 3, 2001
It is revealed that Piper's power is actually the ability to alter the speed of molecules, when her power grows to include the ability to speed up molecules, resulting in uncontrollable explosions. The evil Brotherhood plots to sabotage Cole's relationship with Phoebe in an attempt to turn him back to evil.
Episode 21: Look Who's Barking
Air Date: May 10, 2001
When a spell cast on Prue turns her into a dog, Piper must find a way to track down a Banshee who is killing innocents, and before long, the Banshee succeeds in transforming Phoebe into one of her kind. If Phoebe successfully kills her first innocent, she will remain a Banshee forever, and Piper must now find a way to solve the problem on her own, otherwise she will lose her sisters forever.
Episode 22: All Hell Breaks Loose
Air Date: May 17, 2001
When the Halliwell sisters are exposed as witches on Nation-wide TV, they form a pack with The Source to reverse time and undo the damage. However, in the process, one of the sisters makes the ultimate sacrifice, placing the Power of Three in mortal danger.